Title of article :
Synthesis and crystal structures of copper(I) iodide complexes chelating with bis(ethylamidophosphine)
Author/Authors :
Yat Li، نويسنده , , Ka-Fu Yung، نويسنده , , Hoi-Shan Chan، نويسنده , , Wing-Tak Wong، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
Two copper(I) iodide complexes with polydentate bis(ethylamidophosphine) ligands were synthesized, characterized with crystal structures. They include a dimeric complex [Cu(μ-I)(CH2NHCOC2H4PPh2)2]2 1 containing a planar Cu2I2 rhombohedron with two doubly bridged ligands and a tetrameric complex {Cu4(μ-I)4[(CH2NHCOC2H4PPh2)2]2} 3 with all the coppers and iodines forming a highly distorted cubane geometry.
Keywords :
Copper(I) iodide complex , Cubane , Bis(ethylamidophosphine) , crystal structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications