Title of article
Activation of C–H bond by cis-[Pt(NO3)2(PPh3)2], cyclometallation of tetramethylthiourea
Author/Authors
Serena Fantasia، نويسنده , , Mario Manassero، نويسنده , , Alessandro Pasini، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
4
From page
97
To page
100
Abstract
Reaction of cis-[Pt(NO3)2(PPh3)2] with tetramethylthiourea (tmtu) affords [Pt(PPh3)2(tmtu*)]NO3, in which tmtu* is tetramethylthiourea deprotonated at one methyl group. An X-ray investigation has shown that tmtu* is cyclometallated with Pt–S and Pt–CH2 bonds. The likely role of dissociation of the labile nitrato ligands, to give cationic intermediates, is outlined.
Keywords
Cyclometallated tetramethylthiourea , Platinum-nitrato-phosphine complex , X-ray structure
Journal title
Inorganic Chemistry Communications
Serial Year
2004
Journal title
Inorganic Chemistry Communications
Record number
1316280
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