Author/Authors :
Yu Hou، نويسنده , , Yongge Wei، نويسنده , , Enhong Shen، نويسنده , , Dongrong Xiao، نويسنده , , Enbo Wang، نويسنده , , Shutao Wang، نويسنده , ,
Yangguang Li، نويسنده , , Lin Xu، نويسنده , , Changwen Hu، نويسنده ,
Abstract :
A novel organic–inorganic hybrid vanadium arsenate [(VO)2(HAsO4)2(phen)2] 1 (phen=phenanthroline) has been hydrothermally synthesized and structurally characterized. The title compound contains an unusual 1D ladder-like {V/As/O} chain with the phen ligand directly coordinated to the vanadium arsenate skeleton. To the best of our knowledge, 1 represents the first example of 1D vanadium arsenate decorated with the directly coordinated organic ligands.
Keywords :
crystal structure , Organic–inorganic hybrid , Vanadium arsenate , Hydrothermal synthesis , One-dimensional chain