Title of article :
Chirality of a Strandberg-type heteropolyanion [S2Mo5O23]4−
Author/Authors :
Vaddypally Shivaiah and Samar K. Das، نويسنده , , T. Arumuganathan، نويسنده , , Samar K. Das، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Abstract :
The heteropolyanion [S2Mo5O23]4− having C2 symmetry is dissymmetric and hence expected to be chiral. The heteropoly-compound [NMe4]4[S2Mo5O23] exhibits its both enantiomers in DMSO solution by a Pfeiffer effect when l- and d-arabinose are used as environment substances.
Keywords :
Circular dichroism studies , Strandberg type heteropolyanion , Pfeiffer effect , Recemic mixtures
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications