Author/Authors :
Wen Xu، نويسنده , , Qi Fang، نويسنده , , Hongyu Chen، نويسنده , , Gang XUE، نويسنده , , Guo-Qun Liu، نويسنده , , WENTAO YU، نويسنده , , Jinbiao Zhang، نويسنده , , Cui-Ying Xu، نويسنده , , Deqing Zhang، نويسنده , , Daoben Zhu، نويسنده ,
Abstract :
A new molecular conductor (PyMe)[Ni(dmit)2]2 (PyMe = N-methylpyridinium, dmit = 2-thioxo-1,3-dithiole-4,5-dithiolato) has been synthesized and its structure been determined. The temperature-dependent conductivities in the range of 290–20 K reveal a semi-conducting behavior of the crystal with a small activation energy of 0.067 eV and a quite high room temperature conductivity of 2 S cm−1.
Keywords :
Nickel complex , Synthesis , X-ray crystal structure , Semiconductors
