Title of article
Synthesis, characterization of the dilithium bis-azaallyl complex [CH2C(NAr)C(NAr)CH2]Li2(THF)4 and its catalytic activity for the anionic polymerization of methyl methacrylate
Author/Authors
Longbao Yu، نويسنده , , Yingming Yao، نويسنده , , Qi Shen، نويسنده , , Jie Sun، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
3
From page
542
To page
544
Abstract
The dilithium bis-azaallyl complex [CH2C(NAr)C(NAr)CH2]Li2(THF)4 (Ar=2,6-iPr2C6H3) was synthesized by the reaction of ArNC(CH3)C(CH3)NAr with 2 equiv. of lithium diisopropylamide. This complex exhibits good catalytic activity and stereoselectivity for the anionic polymerization of methyl methacrylate (MMA).
Keywords
lithium amide , crystal structure , Synthesis , Methyl methacrylate , Anionic polymerization
Journal title
Inorganic Chemistry Communications
Serial Year
2004
Journal title
Inorganic Chemistry Communications
Record number
1316404
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