Title of article :
The first discrete mixed-valence hexadecavanadate host shell cluster anions: hydrothermal synthesis, structure and characterization of [V16O38(Cl)]8−
Author/Authors :
Yanhui Chen، نويسنده , , Xiaojun Gu، نويسنده , , Jun Peng، نويسنده , , Zhenyu Shi، نويسنده , , Hongquan Yu، نويسنده , , Enbo Wang، نويسنده , , Ninghai Hu، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Abstract :
A new compound, [NH4]2[Zn(phen)3]2[Zn(phen)2(H2O)2][V16O38(Cl)] · 5H2O (1), was synthesized in the hydrothermal condition. The “naked” [V16O38(Cl)]8− is the first observation with host shell structure in polyoxovanadate chemistry.
Keywords :
Polyoxovanadate , phen , crystal structure , Hydrothermal synthesis
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications