Title of article :
A new polyoxomolybdate infinite chain complex containing β-[Mo8O26]4− linked up by two bonded Ag+ ions: {(Bu4N)2Ag2[Mo8O26]}n
Author/Authors :
Shu-Mei Chen، نويسنده , , Can-Zhong Lu، نويسنده , , Yaqin Yu، نويسنده , , Quan-Zheng Zhang، نويسنده , , Xiang He، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Abstract :
The polyoxomolybdate (Bu4N)2[Mo6O19] reacts with AgNO3 in methanol/dimethylformamide solution to give the complex {(Bu4N)2Ag2[Mo8O26]}n, which contains infinite chain of [Mo8O26]4− linked up only by a pair of Ag ions and displays attractive interactions between the two AgI ions.
Keywords :
Polyoxometalate , sandwich complex , Metal–metal interaction , Coordination mode
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications