Title of article
Synthetic models for active sites of reduced blue copper proteins: minimal geometric change between two oxidation states for fast self-exchange rate constants
Author/Authors
Kiyoshi Fujisawa، نويسنده , , Koyu Fujita، نويسنده , , Tatsuya Takahashi، نويسنده , , Nobumasa Kitajima، نويسنده , , Yoshihiko Moro-Oka، نويسنده , , Yuki Matsunaga، نويسنده , , Yoshitaro Miyashita، نويسنده , , Ken-ichi Okamoto، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
3
From page
1188
To page
1190
Abstract
We have prepared two thiolato copper redox pairs ligated by image as models for blue copper proteins. The kex value of the coordination number invariant Cu(II/I) couples is 51 times faster than that of the coordination number variant Cu(II/I) couples at −20 °C. We also discuss the electron-transfer process.
Keywords
Copper(I) , Hydrotris(pyrazolyl)borate , Blue copper protein , crystal structure , Model complex
Journal title
Inorganic Chemistry Communications
Serial Year
2004
Journal title
Inorganic Chemistry Communications
Record number
1316578
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