Title of article
New crystalline framework formed from a podal ligand with S2O2 donor and CuI: non-interpenetrating square-grid with cubane-like Cu4I4 cluster nodes
Author/Authors
Tae Ho Kim، نويسنده , , Kang Yeol Lee، نويسنده , , Yong Woon Shin، نويسنده , , Seok-Tae Moon، نويسنده , , Ki-Min Park، نويسنده , , Jae Sang Kim، نويسنده , , Youngjin Kang، نويسنده , , Shim Sung Lee، نويسنده , , Jineun Kim، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
27
To page
30
Abstract
Self-assembly of CuI and 1,12-diphenyl-5,8-dioxa-2,11-dithiadodecane (L), a podal ligand with S2O2 donor set, afforded a unique square-grid type coordination polymer [Cu4I4L2]n (1). X-ray analysis of 1 shows that cubane-like Cu4I4 clusters are located at the nodes of the square-grid and connected to four ligands by Cu–S bonds forming a layer structure. The layers are stacked with an ABAB sequence. Photoluminescence behavior of 1 was also investigated.
Keywords
S2O2 podal ligand , Self-assembly , Cu(I) coordination polymer , Square grid , Luminescence thermochromism
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316615
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