Title of article
A novel photoluminescent Ag–terpyridyl complex: one-dimensional linear metal string with double-helical structure
Author/Authors
Lei Hou، نويسنده , , Dan Li، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
3
From page
128
To page
130
Abstract
A novel photoluminescent double-helical complex, [Ag4L4](PF6)4 · (CH3COCH3)2 (1) (L = 4′-phenyl-2,2′:6′,2″-terpyridine) was synthesised and structurally characterised. Argentophilicity (ligand-supported and -unsupported Ag⋯Ag contacts of 2.8441–3.215 Å) plays an important role in determining the infinite metal string and the nature of luminescence.
Keywords
Silver(I) complex , 4?-phenyl-2 , 2?:6? , Argentophilicity , helicate , Metal string , Photoluminescence , 2?-Terpyridine
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316644
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