Title of article
Isolation and authentication of a sodium bispyrazolylaluminate
Author/Authors
Sara Cortes-Llamas، نويسنده , , Miguel-?ngel Vel?zquez-Carmona، نويسنده , , Miguel-?ngel Mu?oz-Hern?ndez، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
155
To page
158
Abstract
Reaction of [Na(Me2pz)(thf)]4 (2) with [(Me2pz)AlMe2]2 in THF generates sodium bispyrazolylaluminate [Na{Al(Me2pz)2Me2}]∞ (1), the first example of a structurally characterized aluminum analog of a polypyrazolylborate. The X-ray structure of complex 1 shows in the solid state unusual Na–CH3–Al bridges and pyrazolyl η5-coordination to sodium.
Keywords
Main group element chemistry , Pyrazolates , Aluminates , Polydentate ligands
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316649
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