Title of article :
A new pseudo Keggin-type polyvanadate image: hydrothermal synthesis and crystal structure
Author/Authors :
Na Hao، نويسنده , , Chao Qin، نويسنده , , Yan Xu، نويسنده , , Enbo Wang، نويسنده , ,
Yangguang Li، نويسنده , , Enhong Shen، نويسنده , , Lin Xu، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
A new pseudo Keggin-type polyvanadate image (1) has been synthesized under hydrothermal condition. The polyoxoanion [H12V13O40]4− of 1 exhibits a classical α-Keggin-type structure, which consists of 12 {VO6} octahedra and a central {VO4} tetrahedron. It is the first pseudo Keggin-type polyvanadate species with mixed VIV/VV metal centers structurally characterized by single-crystal X-ray diffraction hitherto.
Keywords :
Polyoxometalate , Keggin anion , Polyvanadate , Hydrothermal synthesis
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
