Title of article :
Preparation and structural characterization of a dicopper prehelicate
Author/Authors :
Edwin C. Constable، نويسنده , , Catherine E. Housecroft، نويسنده , , Markus Neuburger، نويسنده , , Silvia Schaffner، نويسنده , , Ellen J. Shardlow، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
In the reaction of 4′-(4-ethynylphenyl)-2,2′:6′,2″-terpyridine (3) with trans-[PtI2(PEt3)2] and CuI, ligand 3 scavenges Cu(I) and forms [Cu2(PPh3)2(μ-I)(μ-3)]I, structural characterization of which shows that ligand 3 adopts a helical twist that parallels that found in related double helicates.
Keywords :
Copper(I) , Helicate , Oligopyridine ligand , alkyne , Dinuclear
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
