Title of article
Synthesis and characterisation of a bis(silyloxy)tin(IV) porphyrin
Author/Authors
Steven J. Langford، نويسنده , , Melissa J. Latter، نويسنده , , Jens Beckmann، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
920
To page
923
Abstract
Bis(hydroxy)tin(IV) tetraphenylporphyrin (Sn(IV)TPP(OH)2, 2) condenses with two equivalents of tris(tert-butoxy)silanol (HOSi(OtBu)3, 3) to form complex 2.32 in toluene. The product, which is air and moisture stable, has been characterised by 1H, 29Si and 119Sn NMR spectroscopy and mass spectrometry. Application of this reaction in producing novel photochromic glasses is also discussed.
Keywords
Sn(IV) porphyrins , Silanols , Complexations , NMR spectroscopy
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316841
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