Author/Authors :
Oscar Baldovino-Pantale?n، نويسنده , , Sim?n Hern?ndez-Ortega، نويسنده , , David Morales-Morales*، نويسنده ,
Abstract :
The synthesis of bis-imino nickel(II) NNN pincer complexes of the type [NiCl2{C5H3N-2,6-(CHNArf)2}]; Arf = C6H3-2,3-F2 (1), C6H3-2,5-F2 (2), C6H3-3,4-F2 (3), C6H3-3,5-F2 (4), C6H2-2,3,4-F3 (5), C6H2-2,3,6-F3 (6), C6H2-2,4,5-F3 (7), and C6H2-2,4,6-F3 (8), has been achieved and its reactivity explored proving these compounds to be efficient in the alkyl and aryl thiolation of iodobenzene.
Keywords :
C–S coupling reactions , pincer complexes , Thiolation , Catalysis , crystal structures , nickel complexes
