Title of article
Photochemistry of trichloro(phenylazo)bis(triphenylphosphine)ruthenium(II) induced by Ru to phenyldiazonium MLCT excitation
Author/Authors
Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
2
From page
1185
To page
1186
Abstract
The complex trichloro(phenylazo)bis(triphenylphosphine)ruthenium(II) shows a longest-wavelength absorption at λmax = 520 nm which is assigned to a Ru(II) → phenyldiazonium+ MLCT transition. MLCT excitation leads to the oxidation of the metal and reduction of the diazonium cation which decays to nitrogen and phenyl radical.
Keywords
Electronic spectra , MLCT , Ruthenium , Photochemistry , Phenyldiazonium
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316904
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