Title of article
Photolysis of tetraphenylcyclobutadiene palladium chloride induced by LMCT excitation
Author/Authors
Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
3
From page
248
To page
250
Abstract
The complex tetraphenylcyclobutadiene palladium(IV) chloride shows a longest-wavelength absorption at λmax = 530 nm which is assigned to a LMCT transition from the C4Ph4 dianion to Pd(IV). LMCT excitation leads to the release of Pd(CH3CN)2Cl2 and neutral C4Ph4 which dimerizes to octaphenylcyclooctatetraene.
Keywords
Electronic spectra , Palladium , LMCT , Cyclobutadiene complexes , Photochemistry
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1316966
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