Title of article :
Formation and characterization of a benzoquinolate triplatinum cluster containing a μ3-PPh2 bridging system and two Pt–Pt bonds
Author/Authors :
Alvaro D?ez، نويسنده , , Juan Forniés، نويسنده , , Ana Garc?a، نويسنده , , Elena Lalinde، نويسنده , , M. Teresa Moreno، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
The reaction between [Pt(bzq)(μ-PPh2)]2 and cis-[Pt(C6F5)2(thf)2] (1:2 molar ratio) results in the formation of a bent benzoquinolate triplatinum cluster [Pt3(bzq)(μ-PPh2)2(C6F5)3] 1, which has been characterized by X-ray crystallography. The structure shows the presence of μ2-PPh2 and [μ3-PPh(1,2-η2-Ph)-κ3P] bridging ligands and two platinum–platinum bonds.
Keywords :
Cluster compounds , Platinum , Bridging phosphido ligands , X-ray structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
