Title of article :
The unusual UV absorption behavior of chloro functionalized oligosilane dendrimers
Author/Authors :
C. Krempner، نويسنده , , H. Reinke، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
The unusual UV spectroscopic behavior of the chloro functionalized oligosilane dendrimers [R(Me3Si)2Si–Me2Si]3Si–Cl (3a,b) derived from reactions of R(Me3Si)2Si–K (2a,b) with Cl–Si(SiMe2Cl)3 (1) is reported (a; R = SiMe3 and b; R = Me). The dendritic silanol [Me(Me3Si)2Si][Me(Me3Si)2Si–Me2Si]2Si–SiMe2OH (6) has been isolated as a side product and was characterized by X-ray structure analysis.
Keywords :
Dendrimers , Silanes , Silanols , Clorosilanes , Silicon
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
