Title of article
Complexes of η5, κP-cyclopentadienyl-phosphine ligands by chelate-assisted dehydrofluorinative coupling; the coupling of bis{bis(pentafluorophenyl)phosphino}methane to η5-pentamethylcyclopentadienyl in a rhodium complex
Author/Authors
Andrew C. Marr، نويسنده , , Mark Nieuwenhuyzen، نويسنده , , Ciara L. Pollock، نويسنده , , Graham C. Saunders، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
3
From page
407
To page
409
Abstract
The reaction between [{(η5-C5Me5)RhCl(μ-Cl)}2] and (C6F5)2PCH2P(C6F5)2 in refluxing benzene yields the singly linked complex [{(η5,κP-C5Me 4CH2C6F4-2-P(C6F5)CH2P(C6F5)2)}RhCl2] in which only one phosphorus atom is coordinated to the rhodium.
Keywords
Cyclopentadienyl ligands , Phosphine ligands , fluorinated ligands , C–C coupling
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317007
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