Title of article
Synthesis and structures of novel diastereomeric cyclopalladated ferrocenylimines derived from chiral β-amino alcohols
Author/Authors
Lingzhi Du، نويسنده , , Jun-Fang Gong، نويسنده , , Chen Xu، نويسنده , , Yu Zhu، نويسنده , , Yangjie Wu، نويسنده , , Maoping Song، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
5
From page
410
To page
414
Abstract
Two pairs of novel diastereomeric cyclopalladated ferrocenylimines (Sp, SC)-3 and (Rp, SC)-4 with both planar and central chirality have been synthesized starting from inexpensive and readily available chiral β-amino alcohols. The two pairs of diastereomers were characterized by elemental analysis, IR, 1H NMR and specific rotations. Furthermore, the structures and absolute configurations of complexes (Sp, SC)-3a and (Rp, SC)-4b have been determined by single-crystal X-ray diffraction.
Keywords
crystal structures , Planar chiral palladacycles , Synthesis , Ferrocenylimines , Chiral amino alcohols
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317008
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