Title of article :
A rare mixed-valence state manganese(II/IV) tetranuclear cage formed using phenyl 2-pyridyl ketone oxime and azide as ligands
Author/Authors :
Constantinos J. Milios، نويسنده , , Stergios Piligkos، نويسنده , , Aidan R. Bell، نويسنده , , Rebecca H. Laye، نويسنده , , Simon J. Teat، نويسنده , , Ramon Vicente، نويسنده , , Eric McInnes، نويسنده , , Albert Escuer، نويسنده , , Spyros P. Perlepes، نويسنده , , Richard E.P Winpenny، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Pages :
4
From page :
638
To page :
641
Abstract :
The reaction of Mn(O2CPh)2 · 2H2O with the sodium salt of phenyl 2-pyridyl ketone oxime and sodium azide in MeOH gives a tetranuclear cage with a image core. Magnetic and EPR studies show the cage has an S = 6 ground state.
Keywords :
Magnetic properties , Phenyl 2-pyridyl ketone oxime metal complexes , Cages , End-on azide ligands , EPR spectra , Mixed-valence manganese complex
Journal title :
Inorganic Chemistry Communications
Serial Year :
2006
Journal title :
Inorganic Chemistry Communications
Record number :
1317066
Link To Document :
https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1317066
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