Title of article :
Unexpected metal site selectivity of 1,10-phenanthroline coordination to heterodimetallic PdII–CoII lantern complex
Author/Authors :
Sergei E. Nefedov، نويسنده , , Michael N. Vargaftik، نويسنده , , Ilya I. Moiseev، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
The heterodimetallic lantern complex Pd(μ-OOCMe)4Co(NCMe) is attacked by 1,10-phenanthroline (Phen) on cobalt(II) rather than palladium(II) atom to produce a tribridged binuclear complex Pd(μ-OOCMe)3(OOCMe)Co(Phen) in which the general shape of the PdCo moiety changes only slightly compared to the original tetrabridged structure.
Keywords :
Palladium , Cobalt , Heterodimetallic complex , 1 , 10-Phenanthroline , Coordination
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications