Title of article
Synthesis and characterization of Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(selenosemicarbazone). Crystal structure of a Ni(II) complex with a modified 2,6-diacetylpyridine-bis(selenosemicarbazone)
Author/Authors
Tamara R. Todorovi?، نويسنده , , Alessia Bacchi، نويسنده , , Giancarlo Pelizzi، نويسنده , , Nenad O. Jurani?، نويسنده , , Du?an M. Sladi?، نويسنده , , Ilija D. Br?eski، نويسنده , , Katarina K. Andelkovi?، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
862
To page
865
Abstract
A novel ligand 2,6-diacetylpyridine-bis(selenosemicarbazone) was synthesized and coordinated with Zn(II), Cd(II) and Ni(II). With Zn(II) and Cd(II), the bideprotonated ligand was coordinated as a quinquedentate in trigonal bipyramidal geometry. With Ni(II) during coordination the ligand was modified by elimination of hydrogen selenide and the product was coordinated as a quadridentate forming a square planar complex, the structure of which was determined by X-ray analysis.
Keywords
Selenosemicarbazone derivatives , Ni(II) complexes , X-ray analysis , NMR spectroscopy , Cd(II) , Zn(II)
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317122
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