Title of article :
Spontaneous fixation of CO2 by {Ni9} constructed from tauric anion: Synthesis and X-ray structure of [Ni9(NH2CH2CH2SO3)6(CH3CO2)6(H2O)6(OH)6(μ6-CO3)2]4−
Author/Authors :
Yiming Jiang، نويسنده , , Xiujian Wang، نويسنده , , Xiujü Ying، نويسنده , , Fan Zhong، نويسنده , , Jinhua Cai، نويسنده , , Kunhuan He، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
Nonanuclear nickel(II) cage complex is reported, in which carbonate anions exhibit μ6 coordination mode. The core is arranged as a tricapped trigonal prism of nickel atoms, and held in place by six acetates, six hydroxides and two carbonates.
Keywords :
Nickel complex , Carbonate complex , Polynuclear complex , Fixation of O2 , crystal structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications