Title of article :
The first P–N containing RuCl3NO complex: fac-[RuCl3(NO)(P–N)] (P–N = [o-(N,N-dimethylamino)phenyl]diphenylphosphine)
Author/Authors :
Deividi A. Cavarzan، نويسنده , , F?bio R. Caetano، نويسنده , , Lincoln L. Romualdo، نويسنده , , F?bio B. do Nascimento، نويسنده , , Alzir A. Batista، نويسنده , , Javier Ellena، نويسنده , , Andersson Barison، نويسنده , , M?rcio P. de Araujo، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
Complex fac-[RuCl3(NO)(P–N)] was synthesized from [RuCl3(H2O)2(NO)] in methanol solution under reflux. The orange solid obtained was characterized by NMR (31P{1H}, 1H, 13C) and, cyclic voltammetry, ESI-MS, IR, elemental analysis and X-ray diffraction structure determination. The 31P{1H} reveals the presence of singlet at 36 ppm. IR N–O stretching as KBr pellets or CH2Cl2 solution presented 1866 cm−1 and 1872 cm−1, respectively.
Keywords :
Nitrosyl ruthenium , P–N ligand , X-ray structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
