Title of article
Synthesis and characterization of [Pd{PhP(C6H4-2-SCH2Cl)(C6H4-2-S)}(Ph2PCH2CH2PPh2)]Cl: An example of hemilability and dichloromethane activation
Author/Authors
Valente G?mez-Ben?tez، نويسنده , , Rubén A. Toscano، نويسنده , , David Morales-Morales*، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
6
From page
1
To page
6
Abstract
The stoichiometric reaction of [Pd{PhP(C6H4-2-S)2}(PPh3)] (1) with Ph2CH2CH2Ph2 in dichloromethane (CH2Cl2) as solvent, affords complex [Pd{PhP(C6H4-2-SCH2Cl)(C6H4-2- S)}(Ph2PCH2CH2PPh2)]Cl (2). This specie, being the result of the nucleophilic reaction of a de-ligated thiolate moiety from the fragment [Pd{PhP(C6H4-2-S)2}] with dichloromethane (chloromethylation).
Keywords
Dichloromethane activation , pincer complexes , palladium complexes , Hemilability , Chloromethylation , crystal structures
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317239
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