Title of article :
Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20]
Author/Authors :
Tomas Jelinek، نويسنده , , Bohumir Grüner، نويسنده , , Ivana Cisarova، نويسنده , , Bohumil ?t?br، نويسنده , , John D. Kennedy، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
The reaction of B10H14 with two-electron ligands L to give L2B10H12 is not mimicked by B18H22. Instead, an oxidizing agent is required to introduce a ligand onto the {B18} skeleton: thus deprotonation of syn-B18H22 in monoglyme followed by treatment with I2 and SMe2 gives [7-(SMe2)-syn-B18H20] (41%).☆
Keywords :
Ligand addition , Fused clusters , Macropolyhedral , Ligand-borane complex , X-ray structure , Borane cluster , Oxidative addition of ligand
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
