Title of article :
A novel bismuth ion-bridged chainlike assembly from paradodecatungstate [H2W12O42]10− anions: (NH4)7[Bi(H2W12O42)] · 20H2O
Author/Authors :
Zhen-He Xu، نويسنده , , Xinlong Wang ، نويسنده , ,
Yangguang Li، نويسنده , , En-Bo Wang، نويسنده , , Chao Qin، نويسنده , , Yan-Ling Si، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
A new polyoxotungstate (NH4)7[Bi(H2W12O42)] · 20H2O has been synthesized in aqueous solution and characterized by elemental analysis, IR spectroscopy, TG analysis and single-crystal X-ray diffraction. The most interesting structural feature of 1 is that the paradodecatungstate [H2W12O42]10− anions are linked, for the first time, by the trivalent main group atom BiIII which appeared commonly as a heteroatom in polyoxometalate chemistry, into a one-dimensional chainlike structure.
Keywords :
Polyoxometalates , crystal structure , Tungstate , Bismuth
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
