Title of article
One-dimensional macrocyclic zinc(II) coordination polymer containing an unusual bis-monodentate oxalate bridge
Author/Authors
Hanyoung Park، نويسنده , , Ju Chang Kim، نويسنده , , Alan J. Lough، نويسنده , , Byung Min Lee، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
4
From page
303
To page
306
Abstract
A new zinc(II) complex, {[Zn(L1)(oxalate)] · 3.5H2O}n (1) (L = 5,16-dimethyl-2,6,13,17-tetraazatricyclo[16.4.01,18.07, 12]docosane) has been prepared and characterized by single crystal X-ray structure determination. In 1 the rigidity and steric hindrance of the macrocycle L1 causes the bridging oxalate ligand to coordinate to the zinc(II) ions in an unusual twisted bis-monodentate coordination (1,1′-bicoordination) mode.
Keywords
Oxalate ligand , Coordination polymer , crystal structure , Zinc(II) complex , Tetraazamacrocycle
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317312
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