Title of article
Polymeric coordination system of [Ag2(NO3)2L]n [L = 1,4-bis((cyclohexylthio)acetyl)piperazine] that exhibits supramolecular isomerism with 2D and 3D frameworks
Author/Authors
Tae Ho Kim، نويسنده , , Joobeom Seo، نويسنده , , Ki-Min Park، نويسنده , , Shim Sung Lee، نويسنده , , Jineun Kim، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
5
From page
313
To page
317
Abstract
Depending on the solvents used for crystallization, silver nitrate and the flexible dithioether-type ligand incorporating piperazine diamide [L: 1,4-bis((cyclohexylthio)acetyl)piperazine] readily formed two distinct types of 2D (1) and 3D (2) coordination polymers with identical formula [Ag2(NO3)2L]n. The preparation and structural characterisation of 1 and 2 are reported as an example for the supramolecular isomerism.
Keywords
Dithioether ligand , Coordination polymer , Supramolecular isomerism , Silver(I) complex , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317314
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