Title of article
Inserting sulfur donor ligands in axial positions of an extended trinickel chain
Author/Authors
F. Albert Cotton، نويسنده , , Carlos A. Murillo، نويسنده , , Qingsheng Wang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
3
From page
1088
To page
1090
Abstract
The stoichiometric reaction of [Ni3(dpa)4(CH3CN)2](PF6)2 (1) with NaSPh in dichloromethane, affords the linear trinuclear complex Ni3(dpa)4(SPh)2 (2) in good yield and excellent purity (dpa is the anion of 2,2′-dipyridylamine). This compound represents the first extended metal atom chain (EMAC) with sulfur-containing axial ligands and was characterized by X-ray single-crystal diffraction, elemental analysis, ESI–MS, UV–vis spectrum and magnetic susceptibility measurements.
Keywords
Trinickel complex , Magnetic susceptibility , X-ray crystallography , Sulfur donor ligand , Extended metal atom chains (EMACs)
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317496
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