Title of article
Generation of nitric oxide by photolysis of silver hyponitrite in suspension induced by LMCT excitation
Author/Authors
Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
3
From page
1294
To page
1296
Abstract
The yellow colour of silver hyponitrite is attributed to an LMCT band at λmax = 419 nm. Solid Ag2N2O2 and its suspensions in water or acetonitrile are light sensitive. LMCT excitation leads to a photolysis according to the equation Ag2N2O2 → 2Ag + 2NO. In the presence of air and water, NO is finally converted to HNO2.
Keywords
Electronic spectra , Hyponitrite complexes , Silver complexes , nitric oxide , Photochemistry , LMCT
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317547
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