Title of article :
Cyclopentanone thiosemicarbazone (Hcptsc) induces a new bonding pattern in (Ph3P)Cu(μ-Br)(μ3-S,N–Hcptsc)CuBr(PPh3) dimer
Author/Authors :
Tarlok S. Lobana، نويسنده , , Poonam Kumari، نويسنده , , Ray J. Butcher، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
Reaction of cyclopentanone thiosemicarbazone (Hcptsc) with copper(I) bromide and Ph3P in 1:1:1 molar ratio in acetonitrile has formed an asymmetric dimer, [(Ph3P)Cu(μ-Br)(μ3-S,N–Hcptsc)CuBr(PPh3)] (1), with a new {Cu(μ-Br)(μ3-S,N)Cu} bonding core in metal-thiosemicarbazone chemistry.
Keywords :
Cyclopentanone thiosemicarbazone , Asymmetric dimer , Triphenyl phosphine , Bridging mode , copper
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
