Title of article :
Solvent induced oxidative addition and phenyl migration in trans-[RhCl(CO)(SbPh3)3]: Crystal structure of trans-mer-[Rh(Cl)2(Ph)(SbPh3)3]
Author/Authors :
Stefanus Otto، نويسنده , , Andreas Roodt، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
Phenyl migration and oxidative addition were observed in nitromethane containing solutions of trans-[RhCl(CO)(SbPh3)n] (n = 2 or 3) and free SbPh3. A Rh(III) product resulting from phenyl migration and oxidative addition to Rh(I), trans-mer-[Rh(Cl)2(Ph)(SbPh3)3], was characterised by X-ray crystallography.
Keywords :
Triphenyl antimony , crystal structure , Rhodium , Phenyl migration , Oxidative addition
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
