Title of article :
Extraordinary dissolution of coordination polymer, La[Fe(CN)6] · 5H2O, in ethylene glycol/water mixed solvent and structural determination of dissolved species
Author/Authors :
Aya Nakajima، نويسنده , , Shun Itoh، نويسنده , , Masato Kurihara، نويسنده , ,
Masatomi Sakamoto، نويسنده , , Daisuke Yoshioka، نويسنده , , Masahiro Mikuriya، نويسنده , , Satoshi Hamakawa، نويسنده , , Fujio Mizukami، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
Heteronuclear coordination polymer, La[Fe(CN)6] · 5H2O, poorly soluble in water and almost insoluble in usual organic solvents due to its sturdy three-dimensional infinite network structure constructed by Fe–CN–La linkages was found to be tremendously dissolved in the mixed solvent of ethylene glycol (EG):water = 7:3 to give a highly viscous solution as a promising fluid precursor for the wide application of La[Fe(CN)6] · 5H2O which has been so far utilized only as a solid precursor of LaFeO3. Structure of single crystals isolated from this viscous solution was determined to elucidate the high solubility of La[Fe(CN)6] · 5H2O.
Keywords :
crystal structure , Lanthanum(III) hexacyanoferrate(III) , Solubility , Ethylene glycol complex of lanthanum(III)
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
