Title of article :
{[Cd2(pyt)2(chdc)(H2O)](H2O)2}n: A unique bilayer coordination polymer with mixed-connected network topology (Hpyt = 5-(4-pyridyl)-1,3,4-oxadiazole-2-thiol and H2chdc = 1,4-cyclohexanedicarboxylic acid)
Author/Authors :
Zhihui Zhang، نويسنده , , Cheng-Peng Li، نويسنده , , Yi-Ling Tian، نويسنده , , Ya-Mei Guo، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Pages :
4
From page :
326
To page :
329
Abstract :
A unique CdII coordination polymer {[Cd2(pyt)2(chdc)(H2O)](H2O)2}n (1) has been obtained by hydrothermal reaction and characterized by IR, microanalysis, and powder X-ray diffraction (here Hpyt = 5-(4-pyridyl)-1,3,4-oxadiazole-2-thiol and H2chdc = 1,4-cyclohexanedicarboxylic acid). Single crystal X-ray diffraction reveals that complex 1 has an unusual bilayer coordination framework with mixed-connected network topology, in which two adjacent [Cd(pyt)]n layers are spaced by chdc pillars. Thermal stability of 1 has also been discussed.
Keywords :
Hydrothermal synthesis , crystal structure , Coordination polymer , Bilayer framework , Network topology
Journal title :
Inorganic Chemistry Communications
Serial Year :
2008
Journal title :
Inorganic Chemistry Communications
Record number :
1317690
Link To Document :
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