Title of article :
A cyano-bridged image complex: Synthesis, structure and magnetic properties
Author/Authors :
Yuhua Feng، نويسنده , , Chao Wang، نويسنده , , Gongfeng Xu، نويسنده , , Yan Ouyang، نويسنده , , Daizheng Liao، نويسنده , , Shiping Yan، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
A novel cyano-bridged image complex {Cr(CN)4[CNMn(salen)(MeOH)]2}{[Mn(salen)(CH3OH)(H2O)]2}[Mn(salen)(MeOH)]2[Cr(CN)6] · 6CH3OH (1) (salen = N,N′-ethylene-bis-salicylideneaminato) has been synthesized and structurally characterized. X-ray structure analysis reveals that in 1, except for the trinuclear image unit, there exist two mononuclear MnIII and one dimeric MnIII Schiff-base units. All these structural units are linked by hydrogen bond into a 3D network. The magnetic characterization shows that compound 1 displays a weak ferromagnetic behavior.
Keywords :
Magnetic property , Hydrogen bond , Manganese(III) Schiff-base , Cyano-bridged complex
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
