Title of article
Intraligand fluorescence and phosphorescence of tris(pyrazolyl) hydridoborate complexes
Author/Authors
Horst Kunkely، نويسنده , , Valeri Pawlowski، نويسنده , , Andreas Strasser، نويسنده , , Arnd Vogler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
3
From page
415
To page
417
Abstract
The complexes GdTp3 and PPh3AgTp with Tp = Hydridotris(1-pyrazolyl)borate in the solid state are characterized by rather similar luminescence spectra which consist of a fluorescence near 390 nm and a phosphorescence near 480 nm. These emissions originate from a Tp− ππ∗ IL singlet and triplet, respectively. Owing to the heavy-atom effect of Gd and Ag the phosphorescence appears also at rt.
Keywords
Silver(I) , Gadolinium(III) , Hydrotris(1-pyrazolyl)borate , fluorescence , Phosphorescence
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317712
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