Title of article :
Lead(II)-induced formation and coordination of 3,4-dihydro-3-thioxo-1,2,4-triazin-5(2H)-one
Author/Authors :
José S. Casas، نويسنده , , Eduardo E. Castellano، نويسنده , , Javier Ellena، نويسنده , , Mar?a S. Garc?a-Tasende، نويسنده , , Agust?n S?nchez، نويسنده , , José Sordo، نويسنده , , ?ngeles Touceda، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
Cyclization of nbutyl glyoxylate thiosemicarbazone (HBuTSC) under reflux in the presence of Pb(OAc)2 led to the formation of the complex [Pb(HTz)2] (H2Tz = 3,4-dihydro-3-thioxo-1,2,4-triazin-5(2H)-one), which after recrystallization from DMSO afforded the polymer [Pb(Tz)]n, the first example of a Tz2− metal complex.
Keywords :
Lead(II) complexes , Cyclization of thiosemicarbazones , NMR spectroscopy , Triazinethiones , X-ray diffraction
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
