Title of article
Diastereoselective formation of a complex with an atropisomeric 4,4′-biquinazoline ligand: The solid-state structure of cis-bis(4,4′-biquinazoline)dichloridoiridium(III) hexafluoridophosphate
Author/Authors
Lumni Ademi، نويسنده , , Edwin C. Constable، نويسنده , , Catherine E. Housecroft، نويسنده , , Markus Neuburger، نويسنده , , Silvia Schaffner، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
4
From page
564
To page
567
Abstract
The ligand 4,4′-biquinazoline (biqz) forms complexes in which it adopts either the P or M atropisomeric configuration; the complex cis-[Ir(biqz)2Cl2][PF6] · MeCN has been structurally characterised and shown to comprise a single enantiomeric pair (PM–Δ)(MP–Λ) of the six possible stereoisomers.
Keywords
Chirality , Iridium , 4?-Biquinazoline , Diastereoselectivity , 4 , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317746
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