Title of article
Phosphorescence of permercurated osmocene at ambient conditions
Author/Authors
Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
3
From page
669
To page
671
Abstract
The permercurated osmocene derivative Os[C5(HgOAc)5]2 shows a LF phosphorescence at λmax = 770 nm at ambient conditions. This triplet emission is facilitated by the heavy-atom effect of mercury and, possibly, by the absence of C–H vibrations which may assist radiationless deactivation in osmocene.
Keywords
Heavy-atom effect , Mercury , Osmium , Phosphorescence , Luminescence
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317772
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