Title of article :
Synthesis and characterization of the highest connected 3D α-metatungstate POM/TMC hybrid with AgI⋯AgI interactions
Author/Authors :
Chunjing Zhang، نويسنده , , Ya-Guang Chen، نويسنده , , Haijun Pang، نويسنده , , Dong-Mei Shi، نويسنده , , Mi-Xia Hu، نويسنده , , Jia Li، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
A novel 3D hybrid based on transition metal complexes (TMCs) modified α-metatungstate polyoxometalate (POMs), Na4[Ag6L4][H2W12O40] · 12H2O (1) (L = nicotinate), has been conventionally synthesized and characterized by elemental analysis, IR, UV, TG and single-crystal X-ray diffraction. Each of the W12 clusters is surrounded by 10 Ag centers, which represents the highest connected number of the α-metatungstate POMs to date. Additionally, compound 1 is stable in air and shows photoluminescence at room temperature.
Keywords :
?-Metatungstate polyoxometalate , Conventional synthesis , Silver , Luminescence
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
