Title of article :
Factors that stabilize the image electron configuration in iron(III) porphyrinates: A case of bis(benzaldehyde) complex
Author/Authors :
Akira Ikezaki، نويسنده , , Yoshiki Ohgo، نويسنده , , Taishi Watanabe، نويسنده , , Mikio Nakamura، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
Analysis of the 1H and 13C NMR chemical shifts has revealed that bis-ligated iron(III) porphyrinates, [Fe(Porphyrin)(L)2]±, adopt the image ground state if the complex has highly ruffled porphyrin core and carries weak oxygen ligand with multiple bond such as benzaldehyde.
Keywords :
Iron(III) , Porphyrin complexes , Intermediate-spin , Spin state , Electron configuration
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
