Title of article :
The first anion template cubic cyanometallate cage and its 3,5-dimethyltris(pyrazolyl)methane iron(II, III) tricyanide building blocks
Author/Authors :
Chu-Chen Shi، نويسنده , , Chi-Shian Chen، نويسنده , , Sodio C.N. Hsu، نويسنده , , Wen-Yann Yeh، نويسنده , , Michael Y. Chiang، نويسنده , , Ting-Shen Kuo، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
Several 3,5-dimethyltris(pyrazolyl)methane iron(II, III) tricyanide building units have been prepared and characterized. Treatment of K[(HC(3,5-Me2Pz)3)FeII(CN)2](K+1-) with FeII(H2O)6(BF4)2 affords a new anion template cubic cyanometallate cage [(BF4) ⊂ {FeII(H2O)}4{(HC(3,5-Me2Pz)3)FeII (CN)3}4](BF4)3 3.
Keywords :
crystal structure , Iron complex , Cyanide , 3 , 5-dimethyltris(pyrazolyl)methane
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications