Title of article
Construction of three-dimensional Ln–Ag (Ln = Eu; Tm) coordination polymers based on isonicotinate and oxalate ligands
Author/Authors
Ji-Xia Mou، نويسنده , , Ronghua Zeng، نويسنده , , Yongcai Qiu، نويسنده , , WEIGUANG ZHANG، نويسنده , , Hong Deng، نويسنده , , Matthias Zeller، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
5
From page
1347
To page
1351
Abstract
Hexanuclear 4d–4f heterometallic coordination polymers, [Ln2Ag4(IN)5(ox)2(NO3)(H2O)2 · 3H2O] [Ln = Eu (1), Tm (2); IN = isonicotinate and ox = oxalate], have been synthesized by hydrothermal reaction of mixed organic ligands and metal salts. Both structures display the same unusual 3D heterometallic coordination frameworks based on rare zigzag lanthanide–oxalate–silver chains, Ag2(IN)3 units and IN linkers. The photoluminescent properties of complex 2 were studied.
Keywords
Isonicotinic acid , Ln(III)–Ag(I) heterometallic complexes , Luminescence , Lanthanide–oxalate–silver chains
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317963
Link To Document