Title of article :
Reaction of the titanocene alkyne complex Cp2Ti(η2-Me3SiC2SiMe3) with methanol: Preparation and characterization of a novel trinuclear titanium complex [{Cp2Ti(OMe)}2{Ti(OMe)4}]
Author/Authors :
Perdita Arndt، نويسنده , , Vladimir V. Burlakov، نويسنده , , Christian Fischer، نويسنده , , Detlef Heller، نويسنده , , Marcus Klahn، نويسنده , , Anke Spannenberg، نويسنده , , Uwe Rosenthal، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
The titanocene alkyne complex Cp2Ti(η2-Me3SiC2SiMe3) (1) reacts with methanol to yield depending on the reaction conditions (solvent, temperature) different titanium methoxides [Cp2Ti(OMe)]2 (2a) and [{Cp2Ti(OMe)}2{Ti(OMe)4}] (3). The structure of the trinuclear complex 3, consisting of titanium III and IV, was confirmed by X-ray studies.
Keywords :
titanocene , Ti(III)/Ti(IV) , crystal structure , Methoxide
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
