Title of article
Competition between 3d metals(II) and palladium(II) in the reaction of heterobimetallic complexes Pd(μ-OOCMe)4M(OH2) (M = Ni, Co, Mn) with azobenzene
Author/Authors
Sergei E. Nefedov، نويسنده , , Elena V. Perova، نويسنده , , Ilya A. Yakushev، نويسنده , , Natalia Yu. Kozitsyna، نويسنده , , Michael N. Vargaftik، نويسنده , , Ilya I. Moiseev، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
3
From page
454
To page
456
Abstract
The reaction of PdII(μ-OOCMe)4MII(OH2) (M = Ni, Co, Mn) with azobenzene under mild conditions produces the homonuclear complex with ortho-metallated azobenzene (PhN = NC6H4)2Pd2(μ-OOCMe)2 (4) in higher than 90 % yield as the sole Pd-containing reaction product, while the co-metals are recovered as the corresponding MII acetates.
Keywords
Heterobimetallic paddlewheel complexes , Azobenzene , Palladium , ortho-Metallation , X-ray structure
Journal title
Inorganic Chemistry Communications
Serial Year
2009
Journal title
Inorganic Chemistry Communications
Record number
1318110
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