Title of article
Structure and magnetic properties of a novel branch-like one-dimensional cyano-bridged assembly [Cu(L)]3[Fe(CN)6]2·8H2O (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane)
Author/Authors
Min Ju Cha، نويسنده , , Jong Won Shin، نويسنده , , Young Hoon Lee، نويسنده , , Yang Kim، نويسنده , , Bong Gon Kim، نويسنده , , Kil Sik Min، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
3
From page
520
To page
522
Abstract
The one-dimensional coordination polymer like fern branch, [CuII(L)]3[FeIII(CN)6]2·8H2O (1), which is linked by azamacrocyclic copper(II) complex and iron(III) hexacyanide, has been synthesized and characterized by single crystal X-ray crystallography and magnetic susceptibility measurement (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane). Compound 1 shows a weak ferromagnetic coupling between the copper(II) and low spin iron(III) ions in the one-dimensional chain structure.
Keywords
Coordination polymer , Magnetic properties , Iron(III) hexacyanide , crystal structure , Copper(II) complex
Journal title
Inorganic Chemistry Communications
Serial Year
2009
Journal title
Inorganic Chemistry Communications
Record number
1318128
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